Fast palladium catalyzed arylation of alkenes using bulky monodentate phosphorus ligands

Authors
van Strijdonck, GPF Boele, MDK Kamer, PCJ de Vries, JG van Leeuwen, PWNM
Citation
Gpf. Van Strijdonck et al., Fast palladium catalyzed arylation of alkenes using bulky monodentate phosphorus ligands, EUR J INORG, (7), 1999, pp. 1073-1076
Citations number
38
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
7
Year of publication
1999
Pages
1073 - 1076
Database
ISI
SICI code
1434-1948(199907):7<1073:FPCAOA>2.0.ZU;2-V
Abstract
Complex 1b shows an unprecedented high activity in the Heck reaction. Kinet ic studies show that in this system not the oxidative addition but the alke ne coordination/migratory insertion is the rate determining step.