Formation of anionic PdX3(PPh3)(-) complexes by reaction of halide ions with PdX2(PPh3)(2)

Authors
Amatore, C Jutand, A Mottier, L
Citation
C. Amatore et al., Formation of anionic PdX3(PPh3)(-) complexes by reaction of halide ions with PdX2(PPh3)(2), EUR J INORG, (7), 1999, pp. 1081-1085
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
7
Year of publication
1999
Pages
1081 - 1085
Database
ISI
SICI code
1434-1948(199907):7<1081:FOAPCB>2.0.ZU;2-#
Abstract
Halide ions react with PdX2(PPh3)(2) (X = Cl, Br, I) complexes in an equili brated reaction in which the phosphane ligand is substituted by the halide X- to form anionic complexes PdX3(PPh3)(-) in THF and DMF. The equilibrium constants have been determined by cyclic voltammetry.