Applications of photoelectron spectroscopy to molecular properties, 52 - Gas-phase characterization of an unhindered germaimine by UV-photoelectron spectroscopy

Citation
S. Foucat et al., Applications of photoelectron spectroscopy to molecular properties, 52 - Gas-phase characterization of an unhindered germaimine by UV-photoelectron spectroscopy, EUR J INORG, (7), 1999, pp. 1151-1153
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
7
Year of publication
1999
Pages
1151 - 1153
Database
ISI
SICI code
1434-1948(199907):7<1151:AOPSTM>2.0.ZU;2-C
Abstract
An unhindered germaimine has been generated and characterized by the coupli ng of flash vacuum pyrolysis of two different precursors with UV-photoelect ron spectroscopy. The Ge=N unit exhibits two ionizations in the low-energy region, corresponding to the ejection of an electron from the nitrogen atom lone pair and from the pi(Ge=N) orbital, respectively.