Line mixing effects in the nu(3) band of CH3F in helium: Experimental bandshapes and ECS analysis

Line mixing effects have been studied in the v(3) band of CH3F perturbed by helium. Theoretical absorption coefficients are compared to FTIR measureme nts, which were made at room temperature for helium pressure from 1 atm up to 90 atm. The observed strong modifications with respect to additive Loren tzian contributions are explained by line coupling effects. The Infinite Or der Sudden Approximation and the Energy Corrected Sudden Approximation are used in order to account for these effects. The latter gives better agreeme nt: it rather successfully predicts the band shape and the linewidths.