We present a method for the direct measurement of the Wigner-function matri
x for complex vibronic states of a trapped atom, that is suited to analyse
the entanglement between two motional degrees of freedom and the internal e
lectronic dynamics. It is a generalisation of the method for the determinat
ion of vibronic quantum states [S. Wallentowitz, R.L. de Matos Filho, W. Vo
gel, Phys. Rev. A 56, 1205 (1997)] in conjunction with the scheme for the d
irect observation of the Wigner function of a single motional degree of fre
edom [L.G. Lutterbach, L. Davidovich, Phys. Rev. Lett, 78, 2547 (1997)]. Th
e major advantage of the present method is that it reduces the experimental
efforts substantially. On the other hand, it is demonstrated that the nonl
inear vibronic coupling necessary for this method turns out to be its main
limitation.