Surface relief gratings were optically produced on a number of azobenz
ene-based polymer films. The surface grating formation was investigate
d by monitoring the diffraction efficiency and using atomic force micr
oscopy. The effect of the structure of the chromophores on surface mod
ulation was investigated. The surface deformation process depended on
the polarization state of the writing beams. The localized variations
of the light intensity and alteration of the resulting electric field
polarization were essential writing conditions to the formation of the
surface relief gratings. The surface pattern from straight edge diffr
action established that the surface profile of the recorded gratings i
s proportional to negative gradient of the intensity pattern incident
on the polymer film.