Correlated columnar phases: aroylhydrazinato nickel(II) complexes as noveldiscotics

Citation
A. Bacchi et al., Correlated columnar phases: aroylhydrazinato nickel(II) complexes as noveldiscotics, INORG CH C, 2(6), 1999, pp. 255-257
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
6
Year of publication
1999
Pages
255 - 257
Database
ISI
SICI code
1387-7003(199906)2:6<255:CCPANC>2.0.ZU;2-R
Abstract
A series of ligands derived from 2,3-butanedione and mono-, di- and tri-alk oxy substituted benzoylhydrazines is synthesised and characterised; they re act with nickel(II) acetate giving Ni(ligand-2H) square planar complexes, T he complex with six peripheral dodecyloxy sidechains exhibits a columnar (C ol(hd)) mesophase; the X-ray structure of a model complex is also reported. (C) 1999 Elsevier Science S.A. All rights reserved.