The determination of structural units in amorphous Si-B-N-C ceramics by means of Si, B, N and CK-XANES spectroscopy

Authors
Franke, R Bender, S Jungermann, H Kroschel, M Jansen, M
Citation
R. Franke et al., The determination of structural units in amorphous Si-B-N-C ceramics by means of Si, B, N and CK-XANES spectroscopy, J ELEC SPEC, 103, 1999, pp. 641-645
Citations number
17
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
ISSN journal
03682048 → ACNP
Volume
103
Year of publication
1999
Pages
641 - 645
Database
ISI
SICI code
0368-2048(199906)103:<641:TDOSUI>2.0.ZU;2-W
Abstract
X-ray absorption near edge structure (XANES) measurements at the Si, B, N a nd C K-edges of amorphous Si-B-N-C ceramics were performed to study the loc al atomic structure. Recorded spectra of samples synthesized by a Si-organo polymer synthesis route show the presence of (SiN4), (SiNxCy), (BN3), (NSix By), and (C=C) structural units. The quantitative content of these units de pends on the chemical constitution of the precursor molecules and the react ion conditions. (C) 1999 Elsevier Science B.V. All rights reserved.