Valence-band and conduction-band densities of states (DOSs) of Bi2Y3 (Y=S,
Se, Te) semiconductors have been investigated by means of ultraviolet photo
emission (UPS) and inverse-photoemission spectroscopy (IPES). With the aid
of calculated partial density of states for Bi2Te3 and the UPS and IPES spe
ctra for Bi2Te2Se crystals grown by substituting Te(2) atoms in Bi2Te3 with
Se atoms, we assign the partial DOSs for Bi2Te3 and Bi2Se3. Furthermore, i
t is found that Bi2S3 has the largest band gap (1.1 eV) among these three B
i2Y3 compounds. (C) 1999 Elsevier Science B.V. All rights reserved.