Jm. Harris et Db. Marshall, DIRECT MEASUREMENT OF SORPTION DESORPTION KINETICS IN REVERSED-PHASE CHROMATOGRAPHIC SYSTEMS/, The Journal of microcolumn separations, 9(3), 1997, pp. 185-191
The role of adsorption/desorption kinetics in chromatographic band bro
adening was first addressed by Giddings in his earliest theoretical wo
rk. Relaxation methods (pressure-jump and temperature-jump) have been
adapted to directly measure rates of solute sorption/desorption at rev
ersed-phase chromatographic interfaces. (C) 1997 John Wiley & Sons, In
c.