Experimental evidence at atomic resolution of intra- and intermolecular COcenter dot center dot center dot pi(arene) bond interactions

Authors
Gambaro, A Ganis, P Manoli, F Polimeno, A Santi, S Venzo, A
Citation
A. Gambaro et al., Experimental evidence at atomic resolution of intra- and intermolecular COcenter dot center dot center dot pi(arene) bond interactions, J ORGMET CH, 583(1-2), 1999, pp. 126-130
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
583
Issue
1-2
Year of publication
1999
Pages
126 - 130
Database
ISI
SICI code
0022-328X(19990630)583:1-2<126:EEAARO>2.0.ZU;2-A
Abstract
The crystal data of a number of carbonyl compounds have been reinvestigated . Interactions between carbonyl groups and pi-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agre ement with this interpretation. (C) 1999 Elsevier Science S.A. All rights r eserved.