Citation
Vi. Sokolov et al., Cyclopalladation of phenols in the form of mixed phosphite esters, J ORGMET CH, 582(2), 1999, pp. 246-251
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X
→ ACNP
Volume
582
Issue
2
Year of publication
1999
Pages
246 - 251
Database
ISI
SICI code
0022-328X(19990620)582:2<246:COPITF>2.0.ZU;2-0
Abstract
Phenols can be cyclopalladated after being converted into dialkoxy-O-phosph
ite esters. The usefulness of this novel synthetic method has been demonstr
ated on the examples of natural phenols, L-(+)-tyrosine and (+)-estrone. Th
e molecular structure of cyclopalladated estrone has been determined using
an X-ray method. (C) 1999 Elsevier Science S.A. All rights reserved.