CHIRAL PHOSPHINE-LIGANDS DERIVED FROM SUGARS .8. SYNTHESES OF GOLD(I)COMPLEXES CONTAINING CHIRAL SUGAR PHOSPHINES AND PYRIDINE-1-OXIDE-2-THIOLATE

Authors
SHI JC WEN TB LU GT WU DX LIU QT KANG BS
Citation
Jc. Shi et al., CHIRAL PHOSPHINE-LIGANDS DERIVED FROM SUGARS .8. SYNTHESES OF GOLD(I)COMPLEXES CONTAINING CHIRAL SUGAR PHOSPHINES AND PYRIDINE-1-OXIDE-2-THIOLATE, Journal of coordination chemistry, 41(3), 1997, pp. 199-205
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
41
Issue
3
Year of publication
1997
Pages
199 - 205
Database
ISI
SICI code
0095-8972(1997)41:3<199:CPDFS.>2.0.ZU;2-0
Abstract
Gold(I) compounds [Au(n-MBPA)(2-mpoS)] (2-mpoS = pyridine-1-oxide-2-th iolate; 1, n = 2; 2, n = 3) with a chiral phosphine derived from gluco se (n-MBPA = methyl oxy-n-(diphenylphosphino)-alpha-D-altropyranoside, n = 2, 3) have been prepared and characterized by H-1, C-13 and P-31 NMR and molecular vibration spectroscopy. The spectroscopic data sugge st a monodentate mode of coordination for 2-mpoS ligand through the S donor.