Quantum studies of alignment effects in the Ba(6s6p, P-3(2) <- P-1(1) inelastic transition induced by helium

Citation
E. Paul-kwiek et M. Horodecki, Quantum studies of alignment effects in the Ba(6s6p, P-3(2) <- P-1(1) inelastic transition induced by helium, MOLEC PHYS, 96(12), 1999, pp. 1705-1719
Citations number
42
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR PHYSICS
ISSN journal
00268976 → ACNP
Volume
96
Issue
12
Year of publication
1999
Pages
1705 - 1719
Database
ISI
SICI code
0026-8976(19990620)96:12<1705:QSOAEI>2.0.ZU;2-J
Abstract
The quantum close-coupling studies of the P-3(2) <-- P-1(1) spin-changing t ransitions in Ba(6s6p) colliding with helium involving changes of magnetic quantum numbers are presented. The cross-sections are calculated using the theoretical potential curves of E. Czuchaj et al. [1995, Chem. Phys. Lett., 196, 37]. A description of the characteristic features of the multi-struct ure cross-sections, particularly their dependence on various aspects of col lision dynamics is given. The study of orientation, alignment and coherence effects is made in a range of relative translational energies from thresho ld to 2.0 eV. The calculated multi-structure cross-sections are averaged ov er a Maxwell-Boltzmann distribution of collision energy.