The exciton dissociation in presence of an electric field is investigated i
n light emitting diodes of ladder-type poly(para-phenylene). The experiment
al setup allows us to directly observe the dynamics of the dissociation pro
cess with femtosecond-time resolution. Charge carriers are generated by two
separate mechanisms. For early times, we observe an intra-chain dissociati
on corresponding to breaking during spectral relaxation. For longer times,
we observe a time independent dissociation mechanism due to on-chain dissoc
iation. (C) 1999 Elsevier Science B.V. All rights reserved.