Methods for the synthesis of the Diels-Alder catalysts (ArO)(2)TiX2 (X = Cl, Br, I; Ar=2-tert-butyl-6-methylphenyl)

Authors
Santora, BP White, PS Gagne, MR
Citation
Bp. Santora et al., Methods for the synthesis of the Diels-Alder catalysts (ArO)(2)TiX2 (X = Cl, Br, I; Ar=2-tert-butyl-6-methylphenyl), ORGANOMETAL, 18(13), 1999, pp. 2557-2560
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
13
Year of publication
1999
Pages
2557 - 2560
Database
ISI
SICI code
0276-7333(19990621)18:13<2557:MFTSOT>2.0.ZU;2-8
Abstract
A procedure for converting titanium diethylamidos to the corresponding diha lides (Cl, Br, I) and a complementary method for converting titanium dichlo rides into dibromides and diiodides are reported These methods were utilize d to synthesize a family of homogeneous and polymer-supported Diels-Alder c atalysts with the general formula (ArO)(2)TiX2 (X = Cl, Br, I; Ar =2-tert-b utyl-6-methylphenyl).