We report energy distributions of electrons emitted from Al and Mg surfaces
bombarded by 3-100-keV/amu hydrogen and deuterium ions. The energy spectra
contain structure consistent with the decay of bulk plasmons, even below t
he velocity threshold expected from current theories. To explain the result
s we compare the importance of additional mechanisms involving electron cap
ture, lattice-assisted excitation, and excitation by fast secondary electro
ns.