Phase diagram of star polymer solutions

Citation
M. Watzlawek et al., Phase diagram of star polymer solutions, PHYS REV L, 82(26), 1999, pp. 5289-5292
Citations number
35
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
82
Issue
26
Year of publication
1999
Pages
5289 - 5292
Database
ISI
SICI code
0031-9007(19990628)82:26<5289:PDOSPS>2.0.ZU;2-J
Abstract
The phase diagram of star polymer solutions in a good solvent is obtained o ver a wide range of densities and arm numbers by Monte Carlo simulations. T he effective interaction between the stars is modeled by an ultrasoft pair potential which is logarithmic in the core-core distance. Among the stable phases are a fluid as well as body-centered cubic, face-centered cubic, bod y-centered orthogonal, and diamond crystals. In a limited range of arm numb ers, reentrant melting and reentrant freezing transitions occur for increas ing density.