A new spirostanol saponin was isolated from the underground parts of Ruscus
aculeatus and the structure was assigned as (23S,25R)-spirost-5-ene-3 beta
,23-diol 23-O-{O-beta-D-glucopyranosyl-(1 --> 6)-beta-D-glucopyranoside} on
the basis of spectroscopic analysis, including two-dimensional NMR spectro
scopic techniques and the result of acid hydrolysis. The saponin is unique
in structure having a diglycoside unit at C-23 of the spirostanol skeleton.
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