M. Guziewicz et al., Characteristics of sputter-deposited TiN, ZrB2 and W2B diffusion barriers for advanced metallizations to GaAs, SOL ST ELEC, 43(6), 1999, pp. 1055-1061
The sputter deposition of TIN, ZrB2 and W2B thin films were studied in orde
r to develop the process parameters for advanced metallizations to GaAs dev
ices. Thin films of TiN, ZrB2 and W2B were deposited on both bare and AuZn-
metallized (100) GaAs substrate in magnetron sputtering systems. The resist
ivity and stress in as-deposited thin films were examined and related to de
position conditions. The film microstructure and composition of grown compo
unds were determined by X-ray diffraction, transmission electron microscopy
(TEM) and X-ray photoelectron spectroscopy (XPS). It was observed that met
al boride films were polycrystalline or amorphous depending on the sputteri
ng conditions. Diffusion barrier properties were analyzed by Rutherford bac
kscattering spectroscopy (RBS) technics. (C) 1999 Elsevier Science Ltd. All
rights reserved.