Low temperature x-ray studies of beta '-Pd(dmit)(2) salts

Authors
Rouziere, S Kato, R Aonuma, S Sawa, H
Citation
S. Rouziere et al., Low temperature x-ray studies of beta '-Pd(dmit)(2) salts, SYNTH METAL, 103(1-3), 1999, pp. 1942-1943
Citations number
2
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
103
Issue
1-3
Year of publication
1999
Pages
1942 - 1943
Database
ISI
SICI code
0379-6779(199906)103:1-3<1942:LTXSOB>2.0.ZU;2-V
Abstract
Structure analysis is performed at 8K and room temperature in the isostruct ural salts beta'-(Me(4)Z) [Pd(dmit)(2)](2) and beta'-(Et(2)Me(2)Z)[Pd(dmit) (2)](2) (Z=P,Sb). The temperature effect on the dimerization of the Pd(dmit )(2) molecules is measured. The electronic band calculations show that the two-dimensional HOMO band remains the conduction band at low temperature as the energy gap between the HOMO band and the LUMO band is increased.