Molecular hybrids combining magnetic complexes and organic pi-donors

Authors
Triki, S Berezovsky, F Pala, JS Riou, A Molinie, P
Citation
S. Triki et al., Molecular hybrids combining magnetic complexes and organic pi-donors, SYNTH METAL, 103(1-3), 1999, pp. 1974-1975
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
103
Issue
1-3
Year of publication
1999
Pages
1974 - 1975
Database
ISI
SICI code
0379-6779(199906)103:1-3<1974:MHCMCA>2.0.ZU;2-Z
Abstract
Combination of the magnetic dinuclear chromium(III) anion [Cr-2(C2O4)(NCS)( 8)](4) with the organic ET pi-donor (ET = BEDT-TTF = bis(ethylenedithio)tet rathiafulvalene) yields two novel molecular hybrids (ET)(n) [Cr-2(C2O4)(NCS )(8)] (1 : n = 5; 2. n = 8). The particular arrangement of the organic unit s in the former leads to an unprecedented two-dimensional organic sublattic e nearly similar to that observed in re-phase structures. The packing of th e ET units in 2 is near that observed in beta-phase.