We report a muon spin relaxation study of the organic spin-Peierls system M
EM(TCNQ)(2) over the temperature range 39 mK to 200 K. Our results show a c
rossover from Gaussian to exponential relaxation below the spin-Peierls tra
nsition temperature. We attribute this change to the effect of a dilute set
of static electronic defect spins resulting from the majority of spins fre
ezing into a non-magnetic spin singlet state.