Hybrid-dimensional system in M(dmit)(2) salts

Authors
Hanasaki, N Tajima, H Kato, R Imakubo, T Sawa, H
Citation
N. Hanasaki et al., Hybrid-dimensional system in M(dmit)(2) salts, SYNTH METAL, 103(1-3), 1999, pp. 2086-2086
Citations number
2
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
103
Issue
1-3
Year of publication
1999
Pages
2086 - 2086
Database
ISI
SICI code
0379-6779(199906)103:1-3<2086:HSIMS>2.0.ZU;2-F
Abstract
We report the optical properties of molecular conductor (IEDT)[Pd(dmit)(2)] . We observed a striking peak in the spectral range around 11000 cm(-1) for the Light polarized along the dimeric direction. This peak suggests the st rong dimerization of Pd(dmit)(2) molecules, leading the inversion between H OMO and LUMO energy levels of Pd(dmit)(2). This peak intensity enables to e stimate the charge transfer rho similar to 0.35 from IEDT to Pd(dmit)(2).