Multiheterostructure electroluminescence (EL) devices with blue emission co
lor based on parahexaphenyl (PHP) as the emitting layer and various new org
anic materials as hole and/or electron transport layers (HTL, ETL) were fab
ricated to improve the EL efficiency. We present new ETLs, which were prepa
red via different metal-catalyzed coupling reactions of brominated educts i
n high yields. Utilizing these new organic materials enables us to obtain h
igh performance of blue PHP EL devices with low threshold fields (0.3 MV/cm
) and high external EL quantum efficiencies up to 3.4%.