Properties of polyanilines containing oxyethylene units

Citation
A. Kitani et al., Properties of polyanilines containing oxyethylene units, SYNTH METAL, 102(1-3), 1999, pp. 1173-1173
Citations number
2
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1173 - 1173
Database
ISI
SICI code
0379-6779(199906)102:1-3<1173:POPCOU>2.0.ZU;2-5
Abstract
Novel polyanilines (PAnOE), containing two or three oxyethylene units in th e polymer side chain, were prepared electrochemically. The cyclic voltammog ram of PAnOE showed a reversible redox couple around 0.6 V(vs. SCE) and ano ther redox couple at more negative potentials. The latter couple was attrib uted to then-type doping and undoping reactions. The molecular weights of P AnOE were high (1,000,000), and the conductivity values were about 1 mS/cm. These unique electrochemical and electrical properties were compared with those of poly-N-alkylanilines.