We have synthesized two calix[4]arenes modified at their upper rims by M-su
bstituted pyrrole moieties. This paper reports the first electrochemical ho
mopolymerization of such calix[4]arenes. The films growth is fairly good an
d the obtained polymers are stable to electrochemical cycling. But, electro
chemistry does not allow the detection of complexation of akalines cations
by these calix[4]arenes immobilized at an electrode.