Polymeric networks of copper(II) ions linked by a bridging polynitrile ligand

Authors
Triki, S Pala, JS Riou, A Molinie, P
Citation
S. Triki et al., Polymeric networks of copper(II) ions linked by a bridging polynitrile ligand, SYNTH METAL, 102(1-3), 1999, pp. 1472-1473
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1472 - 1473
Database
ISI
SICI code
0379-6779(199906)102:1-3<1472:PNOCIL>2.0.ZU;2-3
Abstract
Synthesis, crystal structure and magnetic properties of [Cu{C[C(CN)(2)](3)} (en)(2)](n). which arises from reaction of Cu(II) with the highly conjugate d polynitrile C10N62- ligand ( C10N62- = [C{C(CN)(2)}(3)](2-)) in presence of ethylenediamine (en = NH2CH2CH2NH2), are reported. This compound present s a polymeric structure of pseudo-octahedral copper(II) ions bridged by the polynitrile unit C10N62- The magnetic susceptibility data in the 5-300 K r ange can be analysed by a Curie law with C = 0.43 cm(3).K.mol(-1).