Conjugated polyrotaxanes containing coordinating units

Citation
Pl. Vidal et al., Conjugated polyrotaxanes containing coordinating units, SYNTH METAL, 102(1-3), 1999, pp. 1478-1479
Citations number
10
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1478 - 1479
Database
ISI
SICI code
0379-6779(199906)102:1-3<1478:CPCCU>2.0.ZU;2-3
Abstract
A polyrotaxane containing a conjugated backbone has been synthesized via;a copper(I) template and electropolymerisation The reversibility of Cu(I) bin ding is perfect only when lithium is present during copper removal, acting as labile scaffolding. The ability of our structure for other transition me tal ion sensing has also been tested Potential shifts seem to indicate inte ractions between redox active copper centers and the conjugated backbone ar e under study.