Second hyperpolarizabilities of 1-center radicals

Authors
Yamada, S Nakano, M Nishino, M Yamaguchi, A
Citation
S. Yamada et al., Second hyperpolarizabilities of 1-center radicals, SYNTH METAL, 102(1-3), 1999, pp. 1554-1555
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1554 - 1555
Database
ISI
SICI code
0379-6779(199906)102:1-3<1554:SHO1R>2.0.ZU;2-W
Abstract
We study the second hyperpolarizabilities ( gamma) for 1-center radicals, i e., BH3-, CH3 and NH3+. It is found that magnitudes of gamma(\gamma\) of th e radicals are sensitively influenced by features of each charged state. It is also found that electron-correlation dependence of gamma can be related to the resonance structure contributing to the ground state of the molecul es.