Synthesis and properties of dimethoxy-substituted unsymmetrical TTF derivatives

Authors
Nishikawa, H Misaki, Y Yamabe, T Shiro, M
Citation
H. Nishikawa et al., Synthesis and properties of dimethoxy-substituted unsymmetrical TTF derivatives, SYNTH METAL, 102(1-3), 1999, pp. 1693-1694
Citations number
9
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1693 - 1694
Database
ISI
SICI code
0379-6779(199906)102:1-3<1693:SAPODU>2.0.ZU;2-8
Abstract
Preparation of a series of unsymmetrical tetrathiafulvalenes substituted wi th two methoxy groups (2a-f), and their electrochemical properties are desc ribed. X-Ray crystal structure analysis of methylenedithio derivative 2c re veals that there are side-by-side S...S contacts shorter than the sum of th e van der Waals radii (3.70 Angstrom). The TCNQ complex of ethylendithio-2 (2d) and I-3 salt of 2e showed low conductivity of 10(-5) S cm(-1) at room temperature.