Citation
M. Giffard et al., Ionic species derived from tetrathiafulvalenes (TTFs): cation-radicals vs cations, SYNTH METAL, 102(1-3), 1999, pp. 1713-1713
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779
→ ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1713 - 1713
Database
ISI
SICI code
0379-6779(199906)102:1-3<1713:ISDFT(>2.0.ZU;2-T
Abstract
Action of acids on TTFs affords cation radicals or/and protonated species,
depending on conditions and substituents. The reaction of TTF derivatives w
ith acids has been monitored using W-Vis and nmr spectroscopy. Stoichiometr
ic cation-radical salts have been synthesized by preparative oxidation of T
TFs using phenyliodoso diacetate and an acid for comparison. A general sche
me for the interaction of TTFs with acids is suggested.