Preparation, X-ray crystal structure, electrical and optical properties ofa new BETS charge transfer salt: kappa-(BETS)(4)Cu2Cl6

Citation
T. Courcet et al., Preparation, X-ray crystal structure, electrical and optical properties ofa new BETS charge transfer salt: kappa-(BETS)(4)Cu2Cl6, SYNTH METAL, 102(1-3), 1999, pp. 1761-1762
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1761 - 1762
Database
ISI
SICI code
0379-6779(199906)102:1-3<1761:PXCSEA>2.0.ZU;2-C
Abstract
Molecular materials with new combinations of properties such as conductivit y and magnetism are attracting great interest. Electrocrystallization of ma terials obtained by association of the organic donor BETS (bis-(ethylenedit hio) tetraselenafulvalene) with copper (II) chlorides leads to several diff erent phases showing coexistence of pi conducting electrons and paramagneti c 3d electrons localised on copper atoms. X-ray crystal structure and condu ctivity measurements of the compound kappa-(BETS)(4)Cu2Cl6 are presented.