Metal complexes with extended TTF dithiolato ligand: PTDT

Authors
Kobayashi, A Kumasaki, M Tanaka, H
Citation
A. Kobayashi et al., Metal complexes with extended TTF dithiolato ligand: PTDT, SYNTH METAL, 102(1-3), 1999, pp. 1768-1769
Citations number
5
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
102
Issue
1-3
Year of publication
1999
Pages
1768 - 1769
Database
ISI
SICI code
0379-6779(199906)102:1-3<1768:MCWETD>2.0.ZU;2-W
Abstract
Novelmonoanionic, dianionic and neutral nickel, copper and palladium comple xes with the extended TTF dithiolato ligand, propylenedithiotetrathiafulval enedithiolate[ptdt(2-)=(S8C9H6)(2-)], have been synthesized-The crystal str uctures of these complexes show the possibility of the electronic band form ation by novel 2D or 3D intermolecular contacts through ptdt ligands. The s ingle crystal of Ni(ptde)(2) revealed an extremely high electrical conducti vity(7 S cm(-1)) at room temperature as a neutral molecular crystal.