We applied femtosecond pump-probe spectroscopy to a guest-host system of co
njugated polymers, the blue-emitting poly(para-phenylene) (m-LPPP) and the
red-emitting poly(perylene-co-diethynylbenzene) (PPDB). Excitation energy t
ransfer between m-LPPP and PPDB, monitored by the formation of the PPDB pho
tobleaching band at 2.15 eV, takes place on a picosecond time scale. The no
nexponential kinetics of the excitation energy transfer and its dependence
on acceptor (PPDB) concentration provide clear evidence for a Forster-type
energy transfer.