We have studied the pressure dependence of the resistivity of undoped polya
cetylene and iodine-doped one up to 2 GPa. X-ray diffraction measurement un
der high pressure was carried out for undoped polyacetylene. Anisotropy in
compression behavior of structure was observed and was found to correspond
with the decrease of electrical resisitivty. Also the influence of pressure
transmitting medium on the structure was observed. The semiconducting beha
vior of iodine-doped polyacetylene was suppressed by pressure but a metalli
c temperature dependence was not obtained.