Photopolymerization of aniline derivatives was revealed to be induced by ph
otoinduced electron transfer (PIET) between tris(2,2'-bipyridyl)ruthenium c
omplex (Ru(bpy)(3)(2+)) and electroactive molecule. Characterization of the
polyaniline prepared should be necessary to compare its potential with che
mically or electrochemically polymerized polyaniline. From the results of c
yclic voltammetry (CV), IR and H-1-NMR analysis, the polymer was identified
as polyaniline. GPC analysis of photopolymerized polyaniline indicated tha
t the polyaniline has molar mass of about several thousands. photopolymeriz
ed polyaniline system was also proposed.