Metallic polyaniline processed from 1,1,1,3,3,3-hexafluoro-2-propanol

Citation
A. Pron et al., Metallic polyaniline processed from 1,1,1,3,3,3-hexafluoro-2-propanol, SYNTH METAL, 101(1-3), 1999, pp. 729-730
Citations number
11
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
101
Issue
1-3
Year of publication
1999
Pages
729 - 730
Database
ISI
SICI code
0379-6779(199905)101:1-3<729:MPPF1>2.0.ZU;2-1
Abstract
We show that PANI(CSA)(0.5), processed from 1,1,1,3,3,3-hexafluoro-2-propan ol (HFIP) exhibits improved chain stacking as evidenced from X-ray diffract ion studies. Films cast from HFIP show metallic type of conductivity down t o 200 K. The temperature dependence of the conductivity can be fitted using a combination of a metallic and hopping contributions in the frame of hete rogeneous disorder picture.