Polymorphism and disorder in oligo- and polyanilines.

Citation
S. Folch et al., Polymorphism and disorder in oligo- and polyanilines., SYNTH METAL, 101(1-3), 1999, pp. 795-796
Citations number
6
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
101
Issue
1-3
Year of publication
1999
Pages
795 - 796
Database
ISI
SICI code
0379-6779(199905)101:1-3<795:PADIOA>2.0.ZU;2-Z
Abstract
The short-range structure and disorder of polyanilines is discussed by cons idering backbone geometry, conformation and sp(2)/sp(3) hybridization of ni trogen atom. The comparison between polymer and oIigomer spectra shows that ring deformation modes are very sensitive to static/dynamic disorder. Low energy Raman and inelastic neutron allow to distinguish two class of emeral dine salts (ES I/ES-II) already distinguished from X-Ray Powder patterns.