Citation
F. Genoud et al., Gas sorption and ESR studies of ageing in PANI-CSA, SYNTH METAL, 101(1-3), 1999, pp. 798-799
Citations number
3
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779
→ ACNP
Volume
101
Issue
1-3
Year of publication
1999
Pages
798 - 799
Database
ISI
SICI code
0379-6779(199905)101:1-3<798:GSAESO>2.0.ZU;2-U
Abstract
The microstructure of polyaniline-CSA films undergoes various modifications
during ageing, as revealed by the changes of the gas sorption characterist
ics. When the adsorbed gas is (paramagnetic) oxygen it results in a broaden
ing of the polaron ESR line, which is proportional to the local conductivit
y. Data of weight uptake and ESR line broadening upon oxygen exposure for s
amples after ageing at 135 degrees C for various times are used to get insi
ght into the ageing process.