Atmospheric CO2 accumulates near the Earth's surface because of relatively
deeper vertical mixing when photosynthesis is active than when it is not. S
ome models simulate an excess of more than 2.5 ppmv CO2 in the remote North
ern Hemisphere due to this "rectification" of an annually balanced terrestr
ial carbon cycle. The covariance between CO2 flux and vertical mixing, and
the resulting vertical structure of CO2 are generally consistent with field
data at local scales, but it is difficult to reconcile such a strong recti
fier signal with current ideas about the global carbon budget. A rectifier
effect of 2.5 ppmv at northern flask sampling stations implies an unreasona
bly strong northern sink of atmospheric CO2, and a corresponding source in
the tropics or Southern Hemisphere.