First synthesis of hunterioside, a novel disaccharide carrying monoterpenoid indole alkaloid, by assembly of three components, tryptamine, secologanin, and a newly-developed glucosyl donor.
O. Ohmori et al., First synthesis of hunterioside, a novel disaccharide carrying monoterpenoid indole alkaloid, by assembly of three components, tryptamine, secologanin, and a newly-developed glucosyl donor., TETRAHEDR L, 40(27), 1999, pp. 5039-5042
The novel structure of hunterioside, the first example of monoterpenoid ind
ole alkaloids carrying a disaccharide, was confirmed by chemical synthesis
starting from tryptamine, secologanin, and a newly-developed gulucosyl dono
r, which selectively gives alpha-gluco type glycosidic linkage in the react
ion with a secologanin derivative. (C) 1999 Elsevier Science Ltd. All right
s reserved.