The AOC (assimilable organic carbon) method was used in this study to evalu
ate the biological stability of potable water. The potable water was drawn
from a waterworks located in a petrochemical industrial area in China. Infr
ared spectra analysis was adopted in this study to examine the relationship
between treatment process and organic compounds in water. By monitoring th
e AOC concentration in groundwater, potable water and the effluent of each
treatment process (biological pretreatment, ozonation, GAC adsorption), the
following were noted: (1) a considerable AOC concentration could still be
detected in potable water after advanced treatment processes, such as ozona
tion and activated carbon adsorption. Relatively poor biological stability
was also noted in the potable water; (2) GAC was the most effective process
with a total AOC removal efficiency of more than 80%. The corresponding bi
otreatment removal efficiency was only 45%. However, ozonation yielded a ne
gative overall removal efficiency of -119%; (3) while biological pre-treatm
ent and GAC adsorption contributed towards a biologically stable water, ozo
nation yielded oxidation products which were biologically unstable. Ozonati
on, if used, should therefore be combined with the GAC or biological proces
ses. Treatment processes (like ozonation) which increased the amount of org
anics in carbonyl group would likely lead to poor product water biological
stability. (C) 1999 Elsevier Science Ltd. Ail rights reserved.