STATE ANALYSIS OF NITROGEN IN CARBON-FILM DERIVED FROM POLYIMIDE KAPTON

Authors
KONNO H NAKAHASHI T INAGAKI M
Citation
H. Konno et al., STATE ANALYSIS OF NITROGEN IN CARBON-FILM DERIVED FROM POLYIMIDE KAPTON, Carbon, 35(5), 1997, pp. 669-674
Citations number
17
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Carbon → ACNP
ISSN journal
00086223
Volume
35
Issue
5
Year of publication
1997
Pages
669 - 674
Database
ISI
SICI code
0008-6223(1997)35:5<669:SAONIC>2.0.ZU;2-U
Abstract
The carbon films prepared from polyimide Kapton were investigated by X PS and elemental analysis. The chemical states of carbon and nitrogen gradually changed with carbonization temperature and the changes in th e peak intensity ratio of I[N1s]/I[C1s] by XPS were consistent with N/ C mole ratios by elemental analysis. The N1s peak around 401 eV which was a main component at 1200 degrees C was considered to correspond to quaternary species such as a pyrrole type nitrogen. This species may exist in the carbon films prepared at 2000 degrees C and affect their properties. (C) 1997 Elsevier Science Ltd.