The crystal structure of [Ag3WS4I{P(C6H5)(3)}(3)]SP(C6H5)(3) comprises disc
rete neutral [Ag3WS4I{P(C6H5)(3)}(3)] and SP(C6H5)(3) molecules. The [Ag3WS
4I{P(C6H5)(3)}(3)] skeleton is cubane-like and the phosphorus environment o
f the SP(C6H5)(3) molecule is a distorted tetrahedron.