{4,4 '-dimethyl-6,6 '-bis(1-morpholiniomethyl)-2,2 '-[1,2-ethanediylbis(nitrilomethylidene-N)]diphenolato-O,O '}- copper(II) diperchlorate monohydrate

Authors
Raj, SSS Thirumurugan, R Shanmugam, G Fun, HK Manonmani, J Kandaswamy, M
Citation
Sss. Raj et al., {4,4 '-dimethyl-6,6 '-bis(1-morpholiniomethyl)-2,2 '-[1,2-ethanediylbis(nitrilomethylidene-N)]diphenolato-O,O '}- copper(II) diperchlorate monohydrate, ACT CRYST C, 55, 1999, pp. 894-896
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
6
Pages
894 - 896
Database
ISI
SICI code
0108-2701(19990615)55:<894:{'''>2.0.ZU;2-K
Abstract
The crystal structure of the title compound, [Cu(C28H38N4O4)](ClO4)(2).H2O, shows that the Cu-II ion is in a distorted square-pyramidal environment. T he average Cu-O and Cu-N bond lengths are 1.916(2) and 1.936 (3) Angstrom, respectively. Both of the morpholino rings adopt a chair conformation. Even though enough chelating centres are available to coordinate more than one metal atom, because of the steric interaction of the morpholino rings only one Cu atom is coordinated to the ligand.