Diclofenac interactions: tetrakis[mu-2-(2,6-dichloroanilino)phenylacetato]-1 : 2 kappa O-8 : O '-diacetone-1 kappa O,2 kappa O-dicopper(II)(Cu-Cu) acetaldehyde solvate

Authors
Castellari, C Feroci, G Ottani, S
Citation
C. Castellari et al., Diclofenac interactions: tetrakis[mu-2-(2,6-dichloroanilino)phenylacetato]-1 : 2 kappa O-8 : O '-diacetone-1 kappa O,2 kappa O-dicopper(II)(Cu-Cu) acetaldehyde solvate, ACT CRYST C, 55, 1999, pp. 907-910
Citations number
23
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
6
Pages
907 - 910
Database
ISI
SICI code
0108-2701(19990615)55:<907:DIT>2.0.ZU;2-6
Abstract
The structure of the centrosymmetric dimeric copper(II) title compound, [Cu -2(C14H10Cl2NO2)(4)(C3H6O)(2)]. C2H4O, has been determined and compared wit h the structures of analogous O-bridged Cu-II dimers. Polarographic experim ents on aqueous solutions containing a mixture of the Cu-II ion and diclofe nac have been used to determine both the formation constant [1 (1) x 10(8)] and the solubility product [2 (1) x 10(-12)] of the complex.