The red form of [Re(phen)(CO)(3)(H2O)]-CF3SO3 center dot H2O

Authors
Connick, WB Di Bilio, AJ Schaefer, WP Gray, HB
Citation
Wb. Connick et al., The red form of [Re(phen)(CO)(3)(H2O)]-CF3SO3 center dot H2O, ACT CRYST C, 55, 1999, pp. 913-916
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
6
Pages
913 - 916
Database
ISI
SICI code
0108-2701(19990615)55:<913:TRFO[C>2.0.ZU;2-X
Abstract
The coordination geometry of the cations in the red form of aquatricarbonyl (1,10-phenanthroline-N,N')rhenium(I) trifluoromethanesulfonate hydrate, [Re (C12H8N2)(CO)(3)-(H2O)]CF3SO3. H2O, is approximately octahedral, with a fac ial arrangement of the linearly coordinated carbonyl ligands. The phenanthr oline (phen) ligands interleave to form a columnar pi-stacked structure.