Ethylene bis(dimethyldithiocarbamate) and butane-1,4-diyl bis(dimethyldithiocarbamate)

Authors
Jian, FF Zhu, DR Fun, HK Chinnakali, K Razak, IA You, XZ
Citation
Ff. Jian et al., Ethylene bis(dimethyldithiocarbamate) and butane-1,4-diyl bis(dimethyldithiocarbamate), ACT CRYST C, 55, 1999, pp. 940-942
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
6
Pages
940 - 942
Database
ISI
SICI code
0108-2701(19990615)55:<940:EBABB>2.0.ZU;2-3
Abstract
In the crystals of the title compounds, C8H16N2S4, (I), and C10H20N2S4, (II ), the molecules lie about inversion centres. In both structures, the C=S b onds in the two dithiocarbamate units are oriented traits to each other. In (I), the ethylene bridge and the bridged S atoms adopt a trans planar conf ormation and form a dihedral angle of 84.4(2)degrees with the dimethyldithi ocarbamate plane. The molecule of (II) is nearly planar; in the crystal, th e molecules are arranged in sheets which are stacked, 3.874 (2) Angstrom ap art, parallel to (206) planes.