Absolute configuration of the active stereoisomer of new rice fungicide Carpropamid

Authors
Koketsu, M Kagabu, S Matsuoka, M
Citation
M. Koketsu et al., Absolute configuration of the active stereoisomer of new rice fungicide Carpropamid, ACT CRYST C, 55, 1999, pp. 1025-1027
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
6
Pages
1025 - 1027
Database
ISI
SICI code
0108-2701(19990615)55:<1025:ACOTAS>2.0.ZU;2-9
Abstract
The absolute configuration of the active component of fungicide Carpropamid of a diastereoisomeric mixture was determined to be (1S,3R)-N-[(R)-1-(4-ch lorophenyl)ethyl]-2,2-dichloro-1-ethyl-3-methylcyclopropanecarboxamide, C15 H18Cl3NO TWO molecules are tightly coupled in the crystal. The intermolecul ar hydrogen bonding between C=O and H-N is responsible for this assembly.